APPLICATION NOTE NO. 13-3
Application note in pdf format
Note: This Application Note does not apply to the SBE 43 Dissolved Oxygen Sensor.
Based on the observations of our customers and analyses of oxygen data, Sea-Bird recommends a new value for the coefficient "pcor" used in the calibration equation for polarographic oxygen sensors (Application note 13-1):
pcor = 0.00015, with units of [inverse decibars].
This value should be used in the SEASOFT calibration equation unless a better value can be determined by pressure calibrations of individual sensors against titrated oxygen values. We estimate a residual error in the pressure correction term of less than 0.2 ml/l per 1000 decibars using the new pcor value.
SEASOFT uses the Owens and Millard (JPO 1985) algorithm as a calibration equation. The algorithm incorporates a term for pressure dependence of oxygen permeability of the Teflon membrane:
oxygen concentration = (terms) * exp [pcor * P]
where exp is the natural exponential function and P is pressure measured in decibars.
Sources for estimates of the value of pcor are:
Source pcor value Beckman 1971, MINOS DOM dissolved oxygen sensor
operating and maintenance instructions0.00024 Beckman, Dissolved Oxygen monitor polarographic oxygen sensor,
Technical Memorandum ATO-1019A0.00017 Owens and Millard (1985, J. Physical Oceanog., v15 (5) ) 0.0001438 (typ) Owens and Millard (preprint of JPO 1985), numerical fits of data
from 144 profiles of oxygen data0.000156 (avg) Sea-Bird analysis of oxygen data supplied by customers 0.00014 to 0.00016
Sea-Bird Home Phone: 425-643-9866 Fax: 425-643-9954 E-mail: seabird@seabird.com